Discovered in Daily Skirmish: Old Bones I used Tundra Barbarians, and Catalyst: Frost didn't proc when Broken Bones (both originals and clones) attacked them.
This looks solved, but for the hell of it, I hit the Tundra Barbarian in Beginner Protectorate Battles with Broken Bones' basic attack, and he frosted them all to death. =(