Deflect says "the next time select champion damages this, its diverted to enemy within 8". You could select, say, a kanen alpha, have it damage the champ, and send the damage 8 spaces away.
However, one could target (with deflect) a champ up to 8 spaces away, and then attack a champ on their side with deflect to effectively bounce the attack off the first guy, off yours, and into the farther guy.
It's a little extreme of a scenario, but still a neat little trick than could theoretically be done.
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